Chapter 1Introduction

1.1The Scope of Chemical Engineering Thermodynamics

1.2System and Surroundings

1.3The Chemical State and Fluid Properties

1.4The First Law of Thermodynamics

1.4.1The first law of thermodynamics for controlled mass system

1.4.2The first law of thermodynamics for controlled volume system

1.5The Second Law of Thermodynamics

1.5.1The upper limit for the conversion of heat into work

1.5.2Entropy

1.5.3Mathematical statement of the second law

Problems16Chapter 2Volumetric Properties of Fluids

2.1p.V.T Behavior of Pure Substances

2.2The Equations of State(EOS)of Fluid

2.2.1The EOS of ideal gas

2.2.2Virial equations of state

2.3Cubic Equations of State

2.3.1The van der Waals equation of state

2.3.2The Redlich.Kwong(R.K)equation of state

2.3.3The Soave.Redlich.Kwong(SRK)equation of state

2.3.4The Peng.Robinson(P.R)equation of state

2.3.5A generic cubic equation of state

2.4Generalized Correlations of Gases

2.4.1Theorem of corresponding states

2.4.2Generalized cubic EOS

2.4.3Two.parameter theorem of corresponding states

2.4.4Three.parameter theorem of corresponding states

2.4.5Generalized correlations of the second virial coefficient

2.5Liquid & Liquid.like Roots of the Generic Cubic EOS

2.6Generalized Correlations for Liquids

Problems47Chapter 3Thermodynamic Properties of Fluids

3.1Property Relations for Homogenous Phases

3.2Calculations of Enthalpy and Entropy

3.3Residual Properties

3.4Residual Properties by EOS

3.5Calculations of Liquid Enthalpy and Entropy

3.6Generalized Property Correlations for Gases

3.6.1Generalized compressibility factor Z for residual enthalpy and residual

entropy

3.6.2Generalized second virial coefficient for residual enthalpy and residual

entropy

3.7Thermodynamic Diagrams

3.8Tables of Thermodynamic Properties

3.9T.S Diagrams

3.9.1Heating and cooling processes at isopiestic pressure

3.9.2Throttling expansion processes

3.9.3Isentropic expansion or compression processes

3.10p.H Diagrams

3.11H.S Diagrams

Problems75Chapter 4Thermodynamic Properties of Mixtures

4.1The Mixing Rules

4.2The Calculations of Vm,mix and Zmix

4.2.1Amagat’s law(part volume law)combined with Z graphs

4.2.2EOS for a mixture of real gases

4.3The Calculations of HR and SR

4.3.1The calculations of HR and SR by EOS

4.3.2The calculations of HR and SR by generalized correlation graphs

Problems90Chapter 5Solution Thermodynamics

5.1Property Relations for Open Systems and Chemical Potential

5.2Partial Properties

5.3Fugacity and Fugacity Coefficient

5.3.1Fugacity calculations for pure gases

5.3.2Fugacity calculations for pure liquids

5.3.3Fugacity calculations for species in solution

5.3.4Application of Microsoft Excel in the thermodynamic property calculations

5.4The Ideal Solution and Standard State

5.5Excess Properties and Property Change in Mixing

5.5.1Excess properties

5.5.2Property change in mixing

5.5.3H.x graph

5.6Activity and Activity Coefficient

5.6.1The Wohl type equations

5.6.2The gamma equation based on local composition

5.6.3The UNIQUAC and UNIFAC model

Problems136Chapter 6Phase Equilibrium

6.1The Criterion of Phases Equilibrium

6.2Vapor.Liquid Equilibrium

6.2.1VLE under low pressures

6.2.2VLE under moderate pressures

6.2.3VLE under high pressures

6.3Gas.Liquid Equilibrium

6.4Liquid.Liquid Equilibrium

6.4.1LLE phase diagrams

6.4.2The stability of liquid solution

6.4.3LLE calculations

6.5Vapor.Liquid.Liquid Equilibrium (VLLE)

Problems178Chapter 7Thermodynamics of Flow Process

7.1Conservation of Mass

7.2Conservation of Energy

7.3Entropy Balance

7.3.1Concept of entropy

7.3.2Entropy balance

7.4Processes Analyzed by Thermodynamics Methods

7.4.1Fluid flowing

7.4.2Compression process

7.4.3Expansion process

7.4.4Throttling process

Problems209Chapter 8Thermodynamics Cycle

8.1Carnot.Cycle and Its Anticlockwise Cycle

8.2Rankine.Cycle & Steam Power Plant

8.2.1Improving of the Carnot engine

8.2.2Improving of the Rankine engine

8.3Vapor Compression Refrigeration Cycle

8.4Absorption Refrigeration

8.5Heat Pump

8.5.1A brief historical development of heat pumps

8.5.2Vapor compression HP

8.5.3Absorption heat pump

Problems242Chapter 9Thermodynamic Analysis of Processes

9.1Ideal Work

9.1.1Non.flowing process

9.1.2Steady.state flow process

9.2Lost Work

9.3Typical Problems

9.3.1Tube flow

9.3.2Heat transfer

9.4 Energy Optimization

Problems252Appendix

Appendix AConversion Factors and Values of the Gas Constant

Appendix BProperties of Pure Species

Appendix CHeat Capacities and Property Changes of Formation

Appendix DThe Lee/Kesler Generalized Correlation Tables

Appendix ESteam Tables

List of Symbols

Selected Glossary in Chemical Engineering Thermodynamics with Chinese Translation

References