有機反應機理的書寫藝術
作 者: (美)格羅斯曼(Grossman, R.B.) 著作
定 價: 80
出?版?社: 科學出版社
出版日期: 2012年01月01日
頁 數: 355
裝 幀: 平裝
ISBN: 9787030333018
●Preface to the Student
●Preface to the Instructor
●1 The Basics
●1.1 Structure and Stability of Organic Compounds
●1.1.1 Conventions of Drawing Structures;Grossman’S Rule
●1.1.2 Lewis Structures;Resonance Structures
●1.1.3 Molecular Shape;Hybridization
●1.1.4 Aromaticity
●1.2 BrCnsted Acidity and Basicity
●1.2.1 PK Values
●1.2.2 Tautomerism
●1.3 Kinetics and Thermodynamics
●1.4 Getting Started in Drawing a Mechanism
●1.5 Classes of Overall Transformations
●1.6 Classes of Mechanisms
●1.6.1 Polar Mechanisms
●1.6.2 Free.Radical Mechanisms
●1.6.3 Pericyclic Mechanisms
●1.6.4 Transition-Metal-Catalyzed and-Mediated Mechanisms
●1.7 Summary......
內容簡介
該書主要講述面對一個有機化學變化如何正確寫出它的反應機理。全文是按照不同反應機理和反應條件安排的,而不同於市面上常見的同類書。該書重點放在用統一的原理將不同的反應聯繫起來。每一章都列舉了常見的反應機理路徑和描述指導。經常遇見對問題和會以"常見錯誤提示"被提及,以此來避免讀者陷入對概念理解的誤區。
he
C
and
N
atoms
in
CH3'and
NH4+both
have
formalpositive
charges.but
the
C
atom
is
electron-deficient,and
the
N
atom
is
not.The
C
and
B
atoms
in
CH3
and
BF3
are
"