●Preface to second edition page xii
●Preface to first edition xiii
●1 Basic concepts of thermodynamics 1
●1.1 External state variables 1
●1.2 Internal state variables 3
●1.3 The first law of thermodynamics 5
●1.4 Freezing-in conditions 9
●1.5 Reversible and irreversible processes 10
●1.6 Second law of thermodynamics 13
●1.7 Condition of internal equilibrium 17
●1.8 Driving force 19
●1.9 Combined first and second law 21
●1.10 General conditions of equilibrium 23
●1.11 Characteristic state functions 24
●1.12 Entropy 26
●2 Manipulation of thermodynamic quantities 30
●2.1 Evaluation of one characteristic state function from another 30
●2.2 Internal variables at equilibrium 31
●2.3 Equations of state 33
●2.4 Experimental conditions 34......
內容簡介
本書主要內容為現代計算機應用觀點下的熱力學基本原理。 化學平衡和化學變化的理論基礎也是本書的內容之一，其重點在於相圖的性質。本書從基本原理出發，討論延及多相的繫統。第二版新增加的內容包括不可逆熱力學、極值原理和表面、界面熱力學等等。 平衡條件的理論刻畫、繫統的平衡狀態和達到平衡時的變化都以圖解的形式給出。 本書適合材料科學與工程領域的研究人員、研究生和高年級本科生閱讀。
