第1章概論(Introduction)1
1.1熱力學的意義 (significance of thermodynamics)1
1.2熱與熱力學(heat and thermodynamics)2
13熱力學的歷史背景(historical background of thermodynamics)3
1.4本書的使用方法(how to use this book) 5
第2章基本概念及熱力學第零定律
(Basic Concepts and the Zeroth Law of Thermodynamics)7
2.1繫統、物質、能量 (system, matter and energy)7
2.1.1繫統(system)7
2.1.2閉口繫統和開口繫統(closed and open systems)7
2.1.3能量的形態(forms of energy)8
2.1.4能量的宏觀及微觀形態
(macroscopic and microscopic forms of energy)8
2.1.5內能(internal energy)9
2.2熱力學的微觀解釋 (microscopic understanding of thermodynamics)9
2.2.1質點繫統的內能(internal energy of pointmass system)9
2.2.2分子運動和物質的狀態及相變
(molecular motions, states of matter and phase changes)10
2.3溫度與熱平衡(熱力學第零定律)
(temperature and thermal equilibrium (the zeroth law of thermodynamics))12
2.3.1熱平衡(熱力學第零定律)
(thermal equilibrium, the zeroth law of thermodynamics)12
2.3.2溫度(temperature)13
2.4熱量和比熱 (heat and specific heat)13
2.5狀態量 (quantity of state)14
2.6單位制和單位(system unit, unit)14
2.6.1SI(the international system of units)14
2.6.2SI以外的單位制和單位(other system of units)16
第3章熱力學第一定律(The First Law of Thermodynamics)19
3.1熱與功 (heat and work)19
3.1.1熱(heat)19
3.1.2功(work)19
3.2閉口繫統的熱力學第一定律 (the first law applied to closed system)20
熱力學目錄3.3熱力學平衡與準靜態過程
(thermodynamic equilibrium and quasistatic process)23
3.3.1熱力學平衡(thermodynamical equilibrium)23
3.3.2準靜態過程(quasistatic process)23
3.3.3可逆過程與不可逆過程(reversible and irreversible processes)24
3.4閉口繫統準靜態過程的熱力學第一定律
(the first law applied to quasistatic process of closed system)25
3.4.1熱力學第一定律(the first law of thermodynamics)25
3.4.2準靜態循環過程的淨功
(net work during quasistatic process of cycle)25
3.4.3定容過程與定壓過程
(specific heats at constant volume and constant pressure)26
3.5開口繫統的熱力學第一定律 (the first law applied to open system)27
3.5.1定常流動繫統的質量守恆定律
(steady flow system and conservation of mass)27
3.5.2流動功與焓(flow work and enthalpy)27
3.5.3定常流動繫統的能量守恆定律
(energy conservation of steady flow system)28
3.5.4各種機械設備中的定常流動繫統
(steady flo