了得網自然科學_無機化學(陸家政)

內容簡介

本書針對藥學類專業無機化學的雙語課程，將無機化學課程的基本內容進行精選,結合國內高校教學實際，刪除原版教材中大量的復雜、繁瑣及較深奧的部分，力求使之既能體現無機化學課程的專業基礎課特色，又可提高學生的英語應用能力。
鋻於醫藥學專業學生理論與實驗課程並重的特點，全書包含兩大部分：Ⅰ Inorganic Chemistry與Ⅱ Inorganic Chemical Experiments。Part Ⅰ includings thirteen chapters:1 Introduction,2 Structures of Atoms,3 Chemical bonds,4 Thermochemistry,5 Chemical Kinetics,6 Chemical Equilibrium,7 Solutions,8 Solubility Equilibrium,9 AcidBase Equilibria，10 An Introduction to Electrochemistry,11 Chemistry of Coordination Compounds,12 Nonmetals and Semimetals,13 Metals。Part Ⅱ includings three chapters:1 Basic Techniques of Experimental Chemistry,2 Typical Chemical Laboratory Apparatus,3 Experiments。
本書可作為高等院校本科藥學及化學類相關專業的無機化學雙語教材，也可作為化學專業英語課的教材或參考書。

作者簡介

無

ⅠInorganic Chemistry1
Chapter 1Introduction2
11Observations and Conclusions3
12The Scientific Method3
13Units of Measurement5
14Advice on Studying Chemistry8
Key Words8
Chapter 2Structures of Atoms9
21Particles in Atoms10
22The Bohr Model12
23The Wave Theory of Electrons13
24Heisenbergs Uncertainty Principle14
25The Schrdinger Equation14
26Quantum Numbers15
27Shapes of Atomic Orbitals17
28ManyElectron Atoms19
29Valence Electrons24
210The Periodic Table and Electronic Configurations of Atoms24
211The Periodicity of the Properties of Elements and Atomic Structure26
Key Words30
Exercises31
Chapter 3Chemical bonds33
31Ionic Bonds33
32Covalent Bonds35
33Lewis Dot Symbols and Lewis Structure37
34Sigma and Pi Bonds43
35Bond Polarity44
36Bond Energy, Bond Length and Bond Angle45
37Molecular Geometry47
38The VSEPR Model47
39Hybrid Orbitals51
310Molecular Orbitals56
311Intermolecular Force64
Key Words71
Exercises71
Chapter 4Thermochemistry74
41First Law of Thermodynamics74
42Enthalpy and Enthalpy Change75
43Hesss Law76
44Entropy and the Second Law of Thermodynamics 79
45Spontaneous Processes and Gibbs Free Energy80
46Temperature and Direction of Spontaneous Change81
47Standard Free Energy of Formation and Standard Free Energy of Reaction82
Key Words83
Exercises83
Chapter 5Chemical Kinetics85
51Reaction Rates85
52Theories of Reaction Rates 87
53Effect of Concentration on Rate of Reaction89
54Rate and Temperature92
55Catalysis94
Key Words95
Exercises96
Chapter 6Chemical Equilibrium98
61Concept of Equilibrium98
62Equilibrium Constant98
63Le Chteliers Principle103
Key Words106
Exercises106
Chapter 7Solutions108
71Ways of Expressing Concentration108
72Colligative Properties113
Key Words124
Exercises125
Chapter 8Solubility Equilibrium127
81Saturated Solutions and Solubility127
82Solubility Equilibria127
83Factors Affecting Solubility130
84Predicting Precipitation Reaction132
85Selective Precipitation134
86Application of Precipitate on Medicine137
Key Words138
Exercises139
Chapter 9AcidBase Equilibria141
91Acids and Bases141
92Ion Product of Water143
93Strength of Weak Acids and Bases144
94The pH of Weak Acids and Bases146
95The CommonIon Effect148
96Buffer Solutions150
Key Words153
Exercises153
Chapter 10An Introduction to Electrochemistry155
101OxidationReduction Reactions155
102Balancing OxidationReduction Equations158
103Voltaic Cells161
104Standard Cell Electromotive Force164
105Electrochemistry and Thermodynamics171
106Effect of Concentration on Cell EMF172
107Reduction Potential Diagrams of Elements(Latimer Diagrams)174
Key Words177
Exercises177
Chapter 11Chemistry of Coordination Compounds180
111The History of Coordination Chemistry180
112Formation of Coordination Compound182
113Nomenclature of Coordination Compounds184
114Structure and Isomerism 185
115Coordination Equilibrium in Solution187
116Valence Bond Theory of Coordination Compounds191
117The Crystal Field Theory194
118The Biological Effects of Coordination Compounds199
Key Words200
Exercises201
Chapter 12Nonmetals and Semimetals203
121General Concepts203
122Hydrogen203
123Boron204
124The Group ⅣA Elements，the Carbon Group Elements205
125The GroupⅤA Elements，the Nitrogen Group Elements208
126The Group ⅥA Elements，the Oxygen Group Elements211
127The Group ⅦA Elements，the Halogens215
128The Group ⅧA Elements，the Noble Gases218
Key Words218
Exercises219
Chapter 13Metals 220
131The Group IA Elements220
132The Group ⅡA Elements224
133The Group ⅢA Elements229
134A Survey of Transition Metals232
135Chemistry of Some Transition Metals234
Key Words239
Exercises239
ⅡInorganic Chemical Experiments241
Chapter 1Basic Techniques of Experimental Chemistry242
11Safety242
12Recording Results243
13Weighing243
14Concerning Liquids244
Chapter 2Typical Chemical Laboratory Apparatus 252
Chapter 3Experiments254
31Some Elementary Operation254
32AcidBase Titration256
33Electrolyte Solutions259
34Preparation of Officinal Sodium Chloride and Its Purity Examination 262
35OxidationReduction Reactions267
36Coordination Compounds271
37The Halogens275
38Chromium,Manganese and Iron278
39Copper,Silver,Zinc and Mercury283
310Determination of the Ionization Constant of HAc by pH Meter287
311Preparation of Ammonium Iron(Ⅱ)Sulfate291
312Preparation and Content Determination of Zinc Gluconate294
Appendix296
Reference308

前言

自2001年國家*提倡在高等院校實行雙語教學以來，很多高等院校都為化學及相關專業的本科生開設了無機化學雙語課程。我們在藥學專業無機化學課上也進行了積極嘗試，課程受到學生的廣泛歡迎，但遺憾的是至今很難找到切合相關專業的英文版《無機化學》教材，國外原版教材雖然可保持語言文字上的原汁原味，但往往內容太多，與國內高等院校現行的教學學時相差甚遠；國內學者編著的教材可供選擇的也為數不多。而我們經過幾年的努力，積累了一定的教學經驗,因此，聯合相關院校組織無機化學雙語教學線的教師編寫了本書。
在本書編寫的過程中，對無機化學課程的基本內容進行精選，加強基礎，突出重點。刪除了以往教材中存在的大量的復雜公式和繁瑣計算的推導以及較深奧的理論分析和闡述，力求做到既言簡意賅，又具有較完整的無機化學知識體繫。竭力保持語言上與外版教材的一致性，又能使其內容更精練、通俗易懂，且更切合目前國內相關專業的教學實際。同時力求使之既能體現無機化學課程的專業基礎課特色，又可提高學生的英語應用能力。希望此書的出版能夠起到拋磚引玉的作用，為無機化學雙語教學質量的進一步提高做出貢獻。
全書由陸家政、陳菲主編並統稿。參加編寫理論部分的有：陳麗江(第1章)，曾憲棟(第2、3章)，陳菲(第3章)，蔡秀蘭(第4章)，管小艷(第5章)，蔣京(第6章)，蔣東麗(第7章)，何麗新(第8章)，姚秀瓊(第9章)，曾琦華(第10章)，陸家政(第11章)，賀麗敏(第12章)，伍小雲、李君君(第13章)。實驗部分由陳菲、陸家政、李雪華和賴澤鋒編寫。
本書在編撰過程中得到了多方的支持。其中廣東藥學院教務處將其立項為特色教材予以支持和幫助，在此表示衷心的感謝。
本書可作為高等院校本科藥學及化學類相關專業的無機化學雙語教材，也可作為化學專業英語課的教材或參考書。
鋻於編者的水平和能力有限，書中尚有不妥之處，懇請專家以及使用本書的老師和同學批評指正。
編者
2009年6月

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